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Decades of thermoelectric-materials research are recorded in tens of thousands of papers, but the quantitative results — Seebeck coefficients, conductivities, figures of merit, doping strategies, synthesis conditions — remain locked in unstructured prose, inaccessible to systematic analysis or machine learning. We present a literature knowledge graph that extracts and structures this information at scale. Using large-language-model information extraction over the parsed full text of 10,158 thermoelectric papers, the graph captures 166,178 records across 13 entity types: 22,317 material mentions, 24,121 property measurements, 7,443 dopant/modification records, 32,306 scientific claims, 14,304 experimental conditions, and derived research-coverage, novelty, and failure signals, each attributed to its source paper by DOI and aligned to an OWL ontology. An independent audit on a stratified 300-paper sample gives an extraction precision of 0.97 and a recall of ~0.85 on content-bearing papers. The graph is released in five interoperable formats (CSV, JSON, JSON-LD, RDF/Turtle with 1.11 million triples, and GraphML with 166,178 nodes and 156,020 edges), enabling literature-scale trend analysis, research-gap discovery, and the fusion of literature evidence with computational materials features.