The development of economical and scalable methods for synthesizing high-quality graphene remains a pivotal challenge in materials science. This study presents an efficient approach for synthesizing turbostratic graphene with micron-sized domains from an accessible bioprecursor – activated charcoal – using fast Joule heating. We demonstrate that ultra-rapid thermal annealing (~16.2 kJ/g, up to 3000 K) triggers a phase transition from amorphous carbon to a highly graphitized structure. Comprehensive characterization via SEM, AFM, Raman spectroscopy, and XRD revealed the formation of large flakes with lateral dimensions up to 1.5 µm and thicknesses ranging from 4 to 200 nm. Raman mapping further uncovered a heterogeneous structure with alternating regions exhibiting different degrees of interlayer coupling, characteristic of turbostratic stacking. The key feature of the material is its turbostratic layer stacking, confirmed by the combination of XRD data showing an interlayer distance of 3.436 Å and Raman spectra characteristic of decoupled graphene layers. The synthesized material exhibits excellent electrical transport properties, with a bulk resistivity of 0.51 Ω·cm – an order of magnitude lower than that of the initial charcoal. These findings highlight the potential of the developed method for producing electrode materials for energy storage devices and conductive composites.