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Rapid identification of maize waterlogging is essential for post-disaster agricultural assessment, but most existing methods rely on multi-temporal imagery that is often unavailable immediately after extreme rainfall events. This study proposes SAB-DeepLabV3+, a semantic segmentation model for mapping waterlogged maize from single-date multispectral imagery within pre-extracted maize planting areas. Built on DeepLabV3+, the model integrates three task-specific modules: a Spectral-Spatial Information Enhancement Module to improve feature discrimination under spectral mixing, an Adaptive Multi-Scale Pooling Module to capture heterogeneous patch sizes, and a Boundary Enhancement Module to refine transition zones. A pixel-level dataset containing 12,198 image patches was constructed from 62 multispectral scenes collected across five major maize-producing cities in Heilongjiang Province, China, during 2022–2024. On the test set, SAB-DeepLabV3+ achieved a waterlogged-class IoU of 68.30%, mIoU of 80.37%, mF1 of 88.62%, and OA of 93.49%, outperforming DeepLabV3+. Leave-one-city-out evaluation further produced an average mIoU of 76.56% and a waterlogged-class IoU of 63.45%. These results indicate that single-date high-resolution multispectral imagery can support rapid and reliable maize waterlogging mapping.