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The Effect of Humidity and UV Light Exposure on the Mechanical Properties of PA6 Matrix Reinforced with Short Carbon Fiber and Built by Additive Manufacturing

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Preprints.org
DOI
10.20944/preprints202510.2028.v1

This work presents results of nylon-based composites used in additive manufacturing (AM) exposed during 24, 48, 96, 168, 336, and 504 hours of continuous exposure to UV and 50% humidity. Sample coupons were built on a Markforged Two® printer. To mimic UV exposure, samples were exposed to 253 nm UV light, whereas for humidity, samples were placed at 50% relative humidity and 22°C in a bi-distilled water atmosphere. The effects of said exposure were measured in tensile, Charpy impact energy, mass absorption, and Shore hardness D tests. nylon gained a 5.6% ±0.48 mass after 504 hrs. For Charpy, absorbed energy goes down from 0.463 J/mm^2 to 0.28 J/mm^2 at 504 h of humidity exposure. For Shore D, the variation goes from 59.1±0.82 for zero exposure to 66.8±2.5 at 504 h of UV exposure. Conversely, UV exposure induced an increase in Young’s modulus and Shore hardness, while significantly reducing impact energy to 0.32 J/mm², indicating embrittlement confirmed by SEM analysis. FTIR analysis revealed hydrolytic degradation under humidity and photo-oxidative degradation under UV, affecting N-H and C=O bonds. These findings allow a designer to project a component with mechanical properties according to the last day of service.

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